Apatite crystals from a hybrid cumulative rock from the Western Tatra Mountains were dated at 344 ± 3 Ma.
However, low U, Th and radiogenic Pb concentrations, elevated common Pb and the lack of a U–Th–Pb apatite standard remain significant challenges in dating apatite by LA-ICPMS, and consequently in developing the chronometer as a provenance tool.
This study has determined U–Pb and Th–Pb ages for seven well known apatite occurrences (Durango, Emerald Lake, Kovdor, Mineville, Mud Tank, Otter Lake and Slyudyanka) by LA-ICPMS.
Analytical procedures involved rastering a 10 μm spot over a 40 × 40 μm square to a depth of 10 μm using a Geolas 193 nm Ar F excimer laser coupled to a Thermo Element XR single-collector ICPMS.
These raster conditions minimized laser-induced inter-element fractionation, which was corrected for using the back-calculated intercept of the time-resolved signal.
A Tl–U–Bi–Np tracer solution was aspirated with the sample into the plasma to correct for instrument mass bias.
External standards (Plešovice and 91500 zircon, NIST SRM 610 and 612 silicate glasses and STDP5 phosphate glass) along with Kovdor apatite were analyzed to monitor U–Pb, Th–Pb, U–Th and Pb–Pb ratios Common Pb correction employed the Pb corrections employed either the initial Pb isotopic composition or the Stacey and Kramers model and propagated conservative uncertainties in the initial Pb isotopic composition.
Common Pb correction using the Stacey and Kramers (1975) model employed an initial Pb isotopic composition calculated from either the estimated U–Pb age of the sample or an iterative approach.
This study presents apatite LA-ICP-MS U-Pb age and trace elements concentrations data from different granite types from the Tatra Mountains, Poland.
Apatite from monazite and xenotime-bearing High Tatra granite was dated at 339 ± 5 Ma.
The apatite LREE patterns reflect two types of magmas that contributed to this layered magma series.
Apatite from a hybrid allanite-bearing diorite from the Goryczkowa Unit was dated at 340 ± 4 Ma with apatite LREE depletion reflecting the role of allanite and titanite during apatite crystallization.